Germanium (Ge)

Germanium is a high index material that is used to manufacture Attenuated Total Reflection (ATR) prisms for spectroscopy. Its refractive index is such that Germanium makes an effective natural 50% beamsplitter without the need for coatings. Germanium is also used extensively as a substrate for production of optical filters. Germanium covers the whole of the 8-14 micron thermal band and is used in lens systems for thermal imaging. Germanium can be AR coated with Diamond producing an extremely tough front optic.
 
Product Data -----------------------------------------------------
 
Transmission Range : 1.8 to 23 μm (1)
Refractive Index : 4.0026 at 11 μm (1)(2)
Reflection Loss : 53% at 11 μm (Two surfaces)
Absorption Coefficient : <0.027 cm-1 @ 10.6 μm
Reststrahlen Peak : n/a
dn/dT : 396 x 10-6 /°C (2)(6)
dn/dμ = 0 : Almost constant
Density : 5.33 g/cc
Melting Point : 936 °C (3)
Thermal Conductivity : 58.61 W m-1 K-1 at 293K (6)
Thermal Expansion : 6.1 x 10-6/°C at 298K (3)(4)(6)
Hardness : Knoop 780
Specific Heat Capacity : 310 J Kg-1 K-1 (3)
Dielectric Constant : 16.6 at 9.37 GHz at 300K
Youngs Modulus (E) : 102.7 GPa (4) (5)
Shear Modulus (G) : 67 GPa (4) (5)
Bulk Modulus (K) : 77.2 GPa (4)
Elastic Coefficients : C11=129; C12=48.3; C44=67.1 (5)
Apparent Elastic Limit : 89.6 MPa (13000 psi)
Poisson Ratio : 0.28 (4) (5)
Solubility : Insoluble in water
Molecular Weight : 72.59
Class/Structure : Cubic Diamond, Fd3m
 
Refractive Index and Optical Transmittance curve----
Refractive Index(No = Ordinary Ray):
µm    No µm    No µm    No
2.058    4.102 2.153    4.0919 2.313    4.0786
2.437    4.0708 2.577    4.0609 2.714    4.0562
2.998    4.0452 3.303    4.0369 4.258    4.0216
4.866    4.017 6.238    4.0094 8.660    4.0043
9.720    4.0034 11.04    4.0026 12.00    4.0023
13.02    4.0021
Optical Transmittance Curve of Ge (Reference Data):
germanium-ge Transmittance
 
Special properties of Ge-----------------------------------

It blocks UV and visible light,as well as IR up to about 2μm.

Its high index is desirable for the design of lenses that might not otherwise be possible.

It has nearly the highest density of the IR-transmitting materials, a consideration when designing for weight restricted systems.

It is subject to thermal runaway; the hotter it gets, the more the absorption increases. Pronounced transmission degradation starts at about 100°C and begins rapidly degrading between 200°C and 300°C, resulting in possible catastrophic failure of the optic.

Ge is generally less expensive than ZnSe and Cleartran.

Ge is diamond turnable.

Typeical application: Thermal imaging, FLIR.

Products manufactured:Lenses, Aspheric Lenses, Binary (Diffractive) Lenses, Windows, Optical Beamsplitters, Optical Filters, Wedges.

Surface finish:Typical specifications for surface quality in the infrared are 40-20 or 60-40 scratch dig in the 2 to 7μm spectral region and 60-40, 80-50 or 120-80 scratch- dig for the 7-14μm area, depending upon system performance requirements. Diamond turned surface finishes of 120 Angstroms rms or better are typical.

Surface figure:Surface figure: In the infrared, typical surface figure ranges from 1/2 wave to 2 waves @0.6328μm depending on the system performance requirements.

AR coating options: Typical available coatings for Germanium include BBAR for 3 to 5μm, 8 to 12μm, and the 3 to 12μm spectral regions. Many application specialized bands are possible between the 2 and 14μm.

Product Notes:------------ --------------------------------------

Germanium is grown using the Czochralski technique by a small number of manufacturers in Belgium, USA, China and Russia. The refractive index of Germanium changes rapidly with temperature and the material becomes opaque at all wavelengths a little above 350K as the band gap floods with thermal electrons.

REFERENCES:
(1) Handbook Optical Constants, ed Palik, V1, ISBN 0-12-544420-6
(2) Li, Refractive Index of Germanium etc, J.Phys Chem, V9, p561, 1980
(3) Pearson & Brattain, Proc. Inst. Radio Eng. V43, p1794, 1955
(4) Fine, J.App.Phys, V24, p338, 1953
(5) Wortman & Evans, V36, (1), P153 (1965)
(6) Hawkins, Sherwood, Djotni: Mid IR Filters for astronomical and remote sensing instrumentation. Invited Paper SPIE Conference Glasgow 2008

Data provided is extracted from our technical handbook of materials. While every attempt has been made to verify the source of the information, ultiQuest Technology accept no responsibility for accuracy of data


 Contact
If you have any questions or comments, please contact us by filling-in the mail form.

 
Copyright 1999-2011 Ultiquest Technology Ltd. | Privacy Policy | Terms of Use | Web Mail Site Credits